ISO 16602 Protective Clothing Against Chemicals - Classification, Labelling and Performance Requirements

ISO 16602 Protective Clothing Against Chemicals - Classification, Labelling and Performance Requirements

The ISO 16602 standard, developed by the International Organization for Standardization (ISO), “ISO 16602 Protective clothing against chemicals – Classification, labeling and performance requirements,” describes the minimum performance classification and labeling requirements for protective clothing designed to provide protection against chemicals. Protective clothing covered by the ISO 16602 standard includes, but is not limited to, full coveralls, liquid-proof or spray-proof coveralls, work overalls, jackets, trousers, aprons, work aprons, hoods, arm guards, and shoe and boot covers.

ISO 16602 Protective Clothing Against Chemicals - Classification, Labelling and Performance Requirements

Chemical protective clothing that provides protection against airborne particles is addressed by the ISO 13982-1 standard referenced in this standard. The ISO 16602 standard does not address protection against solid chemicals other than airborne solid particles (for example, it does not address the problem of chemical dust and particles passing through materials and clothing by friction or stretching, or by direct contact of dust or particles with the clothing surface).

The ISO 16602 standard does not address gloves, boots, eye and face protection, and respiratory protection unless they are an integral part of protective clothing. This standard does not address protection against biological or thermal (hot or cold) hazards, ionizing radiation, or radioactive contamination. It also does not address specialized clothing used in hazardous chemical emergencies.

The ISO 16602 standard aims to provide manufacturers of chemical protective clothing with minimum requirements for testing, classifying, and labeling chemical protective clothing. To assist users of products covered by this standard, it provides descriptions of referenced test methods, guidelines for conducting hazard and risk assessments, and recommended performance levels for specific applications.

In short, the ISO 16602 standard is based on a system of six performance types that help determine the level of hazard and provide guidance for the appropriate personal protective equipment to be worn: Specifically, personal protective equipment is assigned a number from one to six depending on how it performs in various situations.

The types have been defined as follows:

  • Type 1: Gas-tight protection against all types of chemicals or gases. Fully enclosed suits providing protection against vapors, gases, and liquids. Includes a respirator (e.g., self-contained breathing apparatus). Penetration rate is less than 0,01%. Ideal for highly toxic gases such as chlorine or ammonia.
  • Type 2: Non-gas-tight protection. Non-gas-tight suits. Similar to Type 1 but maintains positive internal pressure to prevent leakage. Used where complete sealing is not required but high vapor protection is necessary.
  • Type 3: Non-gas-tight protection against liquids or splashes. Liquid-tight suits. Provides protection against strong liquid jets (e.g., high-pressure sprays). Tested with a liquid jet under pressure. Common in chemical handling or decontamination.
  • Type 4: Non-gas-tight protection against liquid chemical splashes. Spray-proof suits. Provides protection against liquid sprays and mist. Tested with a fine spray. Typically used in pesticide application or pharmaceutical production.
  • Type 5: Non-gas impermeable protection against airborne particles. Particle protection. Provides protection against airborne solid particles (e.g., asbestos or radioactive dust). Tested for aerosol leakage.
  • Type 6: Non-gas-tight protection against liquid aerosol particles. Limited splash protection. The lowest level provides protection against light liquid splashes. Tested with low-volume mist. Suitable for low-risk jobs such as painting or cleaning.

Types 1-4 primarily focus on liquid and gas protection, while Types 5-6 focus on particles and limited liquid exposure. Many garments combine types and include additional classes of mechanical protection (such as abrasion, tear, and puncture). Many everyday disposable coveralls fall into the Type 4, 5, or 6 category.

However, no type is better or worse than another, but knowing the working environment is crucial for selecting the correct personal protective equipment (PPE) for the situation. For example, when dealing with dry particles, PPE rated as Type 5 is usually sufficient to protect users. When dealing with infectious agents, such as bloodborne pathogens, certain aerosols, and body fluids, a Type 5 or Type 6 mask is generally required to provide adequate protection.

In short, the ISO 16602 standard defines the minimum performance classification, labeling, and performance requirements for protective clothing designed to protect the user against chemicals in liquid, aerosol, solid, or gaseous form. This standard helps manufacturers test, classify, and label chemical protective clothing consistently worldwide. It is particularly useful in sectors such as chemical manufacturing, emergency response, pharmaceuticals, agriculture, and hazardous waste management.

This new update to the standard is designed as a multi-part series. However, the current version is still widely referenced and used by manufacturers and security professionals worldwide.

The main objectives of this standard are as follows:

  • To provide a unified classification system for chemical protective clothing.
  • Defining performance tests for all materials and garments.
  • Providing clear labeling so users can choose the correct level of protection.
  • To promote international harmonization.

The ISO 16602 standard defines the following tests:

  • The material's resistance to permeability, penetration, and degradation to specific chemicals.
  • Full garment watertightness (jet or spray tests)
  • Mechanical properties: tensile strength, tear strength, abrasion resistance, burst strength
  • Seam strength
  • Ergonomics and practical performance (movement, visibility, etc.)

In conclusion, the ISO 16602 standard provides a clear and internationally accepted framework for the classification and labelling of chemical protective clothing. Its six-type system helps safety professionals select appropriate personal protective equipment for different chemical risks, ranging from fully gas-tight coveralls (Type 1) to basic splash-resistant coveralls (Type 6).

For many years, our organization, with its competent and experienced staff, has been understanding the needs of its clients, providing the advanced testing services they require, and assisting them in the establishment, implementation, and improvement of management systems. Within this framework, we also provide testing services compliant with the ISO 16602 standard.

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